New form of quantum matter discovered

A team of Researchers discovered that sodium bismuthate can exist as a form of quantum matter called a three-dimensional topological Dirac semi-metal (3DTDS). The discovery of what is essentially a 3D version of grapheme, the 2D sheets of carbon through which electrons race at many times the speed at which they move through silicon,  promises exciting new things to come for the high-tech industry, including much faster transistors and far more compact hard drives. This is the first experimental confirmation of 3D Dirac fermions in the interior or bulk of a material, a novel state that was only recently proposed by theorists. “A 3DTDS is a natural three-dimensional counterpart to graphene with similar or even better electron mobility and velocity,” said Yulin Chen, a physicist with Berkeley Lab's Advanced Light Source (ALS) when he initiated the study that led to this discovery, and now with the University of Oxford. "Because of its 3D Dirac fermions in the bulk, a 3DTDS also features intriguing non-saturating linear magnetoresistance that can be orders of magnitude higher than the materials now used in hard drives, and it opens the door to more efficient optical sensors." Chen is the corresponding author of a paper in Science reporting the discovery. The paper is titled “Discovery of a Three-dimensional Topological Dirac Semimetal, Na3Bi”. Two of the most exciting new materials in the world of high technology today are graphene and topological insulators, crystalline materials that are electrically insulating in the bulk but conducting on the surface. Both feature 2D Dirac fermions (fermions that aren't their own antiparticle), which give rise to extraordinary and highly coveted physical properties. Topological insulators also possess a unique electronic structure, in which bulk electrons behave like those in an insulator while surface electrons behave like those in graphene. "The swift development of graphene and topological insulators has raised questions as to whether there are 3D counterparts and other materials with unusual topology in their electronic structure," Chen said. "Our discovery answers both questions. In the sodium bismuthate we studied, the bulk conduction and valence bands touch only at discrete points and disperse linearly along all three momentum directions to form bulk 3D Dirac fermions. Furthermore, the topology of a 3DTSD electronic structure is also as unique as those of topological insulators." The discovery was made at the Advanced Light Source (ALS), a DOE national user facility housed at Berkeley Lab, using beamline 10.0.1, which is optimized for electron structure studies. The collaborating research team first developed a special procedure to properly synthesize and transport the sodium bismuthate, a semi-metal compound identified as a strong 3DTDS candidate by co-authors Fang and Dai, theorists with the Chinese Academy of Sciences. At ALS beamline 10.0.1, the collaborators determined the electronic structure of their material using Angle-Resolved Photoemission Spectroscopy (ARPES), in which x-rays striking a material surface or interface cause the photoemission of electrons at angles and kinetic energies that can be measured to obtain a detailed electronic spectrum. Sodium bismuthate is too unstable to be used in devices without proper packaging, but it triggers the exploration for the development of other 3DTDS materials more suitable for everyday devices, a search that is already underway. Sodium bismuthate can also be used to demonstrate potential applications of 3DTDS systems, which offer some distinct advantages over graphene. "A 3DTDS system could provide a significant improvement in efficiency in many applications over graphene because of its 3D volume," Chen said. "Also, preparing large-size atomically thin single domain graphene films is still a challenge. It could be easier to fabricate graphene-type devices for a wider range of applications from 3DTDS systems."